1. One of carbon's
interesting properties is its ability to form a wide variety of molecules,
especially ones containing bonds linking multiple carbon atoms.
2. This element is
so widely distributed throughout nature that the largest subdiscipline of
chemistry, organic chemistry, is devoted to the study of carbon compounds.
3. The
name organic is historical and suggests a biological origin for the substances
under investigation, but this is not necessarily true.
4. In
practice, most organic chemists confine themselves to compounds in which carbon
is combined with a relatively small number of other elements: hydrogen, oxygen,
nitrogen, sulfur, chlorine, phosphorus, and bromine.
5. Even
with this restriction, over 12 million of the 23 million total known compounds
are considered organic.
6. The
chemical behavior (i.e., properties and reactivity) of organic compounds
enables us to organize them into a relatively small number of categories.
7. As a
result, in this chapter we concentrate on only a few and stress their important
roles within the functions of living things.
8. To
identify a specific organic compound from among the myriad of possibilities,
the compound must be named.
9. Chemists
use a formal set of nomenclature rules established by an international
committee so each of the 12 million compounds can be uniquely named.
10. However, many of
these compounds have been known for a long time by common names such as
alcohol, sugar, and morphine.
11. When a headache
strikes, even chemists do not call out for 2-(acetyloxy)-benzoic acid; they
simply say "Give
me some aspirin!"
12. Likewise,
prescriptions specify penicillin-N rather than 6[(5-amino-5-carboxy-l-oxopentyl)amino]-3,3-dimethyl-7-oxopentyl-4-thia-l-azabicyclo[3.2.0]hepta-ne-2-carboxylic
acid.
13. Mouthfuls like
this are the cause of great merriment to those who like to satirize chemists.
Nonetheless, chemical names are important and unambiguous to those who know the
system.
14. You can rest easy
because in this chapter, we will use common names in almost all cases.
15. An incredible
variety of organic compounds exists because of the remarkable ability of
carbon atoms to bond in multiple ways both to other carbon atoms and to atoms
of other elements.
16. To better
understand such possibilities, we need a few basic rules for bonding in organic
molecules.
17. You used one of
these in Chapter 2, the octet rule.
18. When bonded, each
carbon atom has a share in eight electrons, an octet.